← All Units← 返回单元列表 ← Course Hub← 课程主页
I B  P H Y S I C S  H L
Unit E3 · SolutionsUnit E3 · 解析

Radioactive Decay · Solutions放射性衰变 · 解析

Companion to the IB-Style Practice SetIB 风格练习题的解析配套

MEDIUM HARD Paper 1 Paper 1B Paper 2 HL ONLY

Syllabus E3.1 to E3.6考纲 E3.1 至 E3.6PHYSICS HL



PART I  ·  PAPER 1 STYLE第一部分  ·  第一卷风格Short structured · 30 marks短结构题 · 30 分

Worked Solutions详细解析

Q1MEDIUMPaper 1three radiations: nature, penetration, ionisation三种辐射:本质、穿透、电离[4 marks]

A source emits alpha, beta-minus and gamma. (a) identity and charge of each; (b) order by increasing penetration and how ionising power compares.某源发射 α、β⁻ 与 γ。(a) 各自的本质与电荷;(b) 按穿透力递增排序及电离能力如何对比。

Answers:答案:  (a) $\alpha = {}^{4}_{2}\mathrm{He}$ nucleus $(+2e)$; $\beta^{-} =$ fast electron $(-e)$; $\gamma =$ photon $(0)$  ·  (b) penetration $\alpha < \beta < \gamma$; ionising power is the reverse $\alpha > \beta > \gamma$

(a) Identity and charge A1·A1

Alpha is a helium nucleus ${}^{4}_{2}\mathrm{He}$, two protons and two neutrons, charge $+2e$. (A1)

Beta-minus is a fast-moving electron ${}^{0}_{-1}e$, charge $-e$; gamma is a high-energy photon (electromagnetic radiation), no mass and no charge. (A1)

(b) Penetration and ionisation order A1·A1

In order of increasing penetrating power: alpha (stopped by paper or a few cm of air), then beta (a few mm of aluminium), then gamma (only attenuated by thick lead or concrete). (A1)

Ionising power runs in exactly the reverse order, $\alpha > \beta > \gamma$: the most ionising radiation is the least penetrating. (A1)

Insight. The two rankings are mirror images, and that is not a coincidence: a heavily ionising particle deposits its energy quickly, so it is absorbed over a short range. Alpha, being slow, heavy and doubly charged, rips electrons off atoms aggressively and stops almost at once; gamma, uncharged and massless, interacts weakly and slips deep into matter. Quote both orders and link them with one sentence about energy deposition to secure full marks.

(a) 本质与电荷 A1·A1

α 是氦核 ${}^{4}_{2}\mathrm{He}$,含两个质子与两个中子,电荷 $+2e$。(A1)

β⁻ 是高速运动的电子 ${}^{0}_{-1}e$,电荷 $-e$;γ 是高能光子(电磁辐射),无质量、无电荷。(A1)

(b) 穿透与电离排序 A1·A1

按穿透力递增:α(被纸或几厘米空气挡住),然后 β(几毫米铝),再到 γ(只被厚铅或混凝土减弱)。(A1)

电离能力恰为相反顺序,$\alpha > \beta > \gamma$:电离最强的辐射穿透最弱。(A1)

要点。两个排序互为镜像,这并非巧合:强电离的粒子很快沉积能量,故在短程内被吸收。α 慢、重、带两个正电荷,剧烈地把电子从原子上剥离,几乎立刻停下;γ 不带电、无质量,相互作用弱,能深入物质。写出两个排序,并用一句话以能量沉积把它们联系起来,方可拿满分。
Q2MEDIUMPaper 1balancing nuclear equations + the (anti)neutrino配平核方程与(反)中微子[6 marks]

(a) alpha decay of ${}^{226}_{88}\mathrm{Ra}$; (b) beta-minus decay of ${}^{90}_{38}\mathrm{Sr}$ with the lepton; (c) the two conserved quantities and why an antineutrino is needed. (Rn $Z = 86$; Y $Z = 39$.)(a) ${}^{226}_{88}\mathrm{Ra}$ 的 α 衰变;(b) ${}^{90}_{38}\mathrm{Sr}$ 的 β⁻ 衰变含轻子;(c) 两个守恒量及为何需要反中微子。(Rn $Z = 86$;Y $Z = 39$。)

Answers:答案:  (a) ${}^{226}_{88}\mathrm{Ra} \to {}^{222}_{86}\mathrm{Rn} + {}^{4}_{2}\alpha$  ·  (b) ${}^{90}_{38}\mathrm{Sr} \to {}^{90}_{39}\mathrm{Y} + {}^{0}_{-1}\beta + \bar{\nu}_e$  ·  (c) nucleon number $A$ and charge $Z$; antineutrino conserves lepton number and energy

(a) Alpha decay of radium-226 M1·A1

Alpha emission removes $4$ from the nucleon number and $2$ from the charge: $A = 226 - 4 = 222$, $Z = 88 - 2 = 86$. (M1)

$$ {}^{226}_{88}\mathrm{Ra} \to {}^{222}_{86}\mathrm{Rn} + {}^{4}_{2}\alpha. $$

Element $86$ is radon, so the daughter is ${}^{222}_{86}\mathrm{Rn}$. (A1)

(b) Beta-minus decay of strontium-90 M1·A1

Beta-minus keeps the nucleon number fixed ($A = 90$) and raises the charge by one ($Z = 38 + 1 = 39$); the emitted electron carries $-1$ charge, and an antineutrino accompanies it. (M1)

$$ {}^{90}_{38}\mathrm{Sr} \to {}^{90}_{39}\mathrm{Y} + {}^{0}_{-1}\beta + \bar{\nu}_e. $$

Element $39$ is yttrium, so the daughter is ${}^{90}_{39}\mathrm{Y}$. (A1)

(c) Conserved quantities and the antineutrino A1·R1

Conserved across the arrow: the nucleon number $A$ (top numbers) and the charge $Z$ (bottom numbers). (A1)

The antineutrino is required because the emitted electron is a lepton, so an antilepton must appear to conserve lepton number, and it carries the variable balance of energy and momentum that gives beta particles a continuous energy spectrum. (R1)

Insight. Mark schemes split a balancing question into two independent checks, top row and bottom row, so write both sums explicitly. The (anti)neutrino is the part most often dropped: beta-minus always takes an antineutrino $\bar{\nu}_e$, beta-plus always takes a neutrino $\nu_e$. It changes neither $A$ nor $Z$, which is exactly why a candidate who omits it can still balance the numbers yet lose the final mark.

(a) 镭-226 的 α 衰变 M1·A1

α 发射使核子数减 $4$、电荷减 $2$:$A = 226 - 4 = 222$,$Z = 88 - 2 = 86$。(M1)

$$ {}^{226}_{88}\mathrm{Ra} \to {}^{222}_{86}\mathrm{Rn} + {}^{4}_{2}\alpha. $$

第 $86$ 号元素为氡,故子核为 ${}^{222}_{86}\mathrm{Rn}$。(A1)

(b) 锶-90 的 β⁻ 衰变 M1·A1

β⁻ 使核子数不变($A = 90$)、电荷加 $1$($Z = 38 + 1 = 39$);所发射电子带 $-1$ 电荷,并伴随一个反中微子。(M1)

$$ {}^{90}_{38}\mathrm{Sr} \to {}^{90}_{39}\mathrm{Y} + {}^{0}_{-1}\beta + \bar{\nu}_e. $$

第 $39$ 号元素为钇,故子核为 ${}^{90}_{39}\mathrm{Y}$。(A1)

(c) 守恒量与反中微子 A1·R1

箭头两侧守恒的是核子数 $A$(上标)与电荷 $Z$(下标)。(A1)

需要反中微子,是因为所发射电子是轻子,必须有一反轻子出现以守恒轻子数;它还带走可变的那份能量与动量,使 β 粒子呈现连续能谱。(R1)

要点。评分把配平题拆成两个独立检查,上排与下排,故要把两个和都明确写出。(反)中微子是最易漏写的部分:β⁻ 总配反中微子 $\bar{\nu}_e$,β⁺ 总配中微子 $\nu_e$。它既不改变 $A$ 也不改变 $Z$,这正是考生即使漏写仍能把数字配平、却丢掉最后一分的原因。
Q3MEDIUMPaper 1half-life: the fraction rule半衰期:分数法则[6 marks]

$T_{1/2} = 6.0\ \mathrm{h}$, sample starts with $N_0$ nuclei. (a) meaning of half-life; (b) fraction remaining after $18\ \mathrm{h}$; (c) time to fall to $\tfrac{1}{16}N_0$ and why no log is needed.$T_{1/2} = 6.0\ \mathrm{h}$,样品起始含 $N_0$ 个核。(a) 半衰期含义;(b) $18\ \mathrm{h}$ 后剩余分数;(c) 降到 $\tfrac{1}{16}N_0$ 的时间及为何无需对数。

Answers:答案:  (a) time for half the nuclei to decay  ·  (b) $\tfrac{1}{8}$  ·  (c) $t = 24\ \mathrm{h}$ (4 half-lives)

(a) Meaning of half-life B1

The half-life is the time taken for half the radioactive nuclei in a sample to decay (equivalently, the time for the activity or count rate to halve). (B1)

(b) Fraction after 18 hours M1·A1

Number of half-lives: $n = \dfrac{t}{T_{1/2}} = \dfrac{18}{6.0} = 3$. (M1)

$$ \frac{N}{N_0} = \left(\tfrac{1}{2}\right)^{3} = \tfrac{1}{8}. $$

(A1)

(c) Time to fall to one-sixteenth M1·A1·R1

$\tfrac{1}{16} = \left(\tfrac{1}{2}\right)^{4}$, so $4$ half-lives have passed. (M1)

$$ t = 4 \times T_{1/2} = 4 \times 6.0 = 24\ \mathrm{h}. $$

(A1)

No logarithm is needed because the target fraction is an exact power of $\tfrac{1}{2}$, so the time is a whole number of half-lives. (R1)

Insight. Whenever the remaining fraction is $\tfrac{1}{2},\tfrac{1}{4},\tfrac{1}{8},\tfrac{1}{16},\dots$ the fastest route is to count halvings, not reach for the exponential law. Build the habit of reading $\tfrac{1}{16}$ as $\left(\tfrac{1}{2}\right)^{4}$ on sight. The exponential law in E3.5 is only the tool of last resort, for fractions such as $0.30$ that fall between two halvings.

(a) 半衰期的含义 B1

半衰期是样品中一半放射性核衰变所需的时间(等价地,活度或计数率减半所需时间)。(B1)

(b) 18 小时后的分数 M1·A1

半衰期个数:$n = \dfrac{t}{T_{1/2}} = \dfrac{18}{6.0} = 3$。(M1)

$$ \frac{N}{N_0} = \left(\tfrac{1}{2}\right)^{3} = \tfrac{1}{8}. $$

(A1)

(c) 降到十六分之一的时间 M1·A1·R1

$\tfrac{1}{16} = \left(\tfrac{1}{2}\right)^{4}$,故已过 $4$ 个半衰期。(M1)

$$ t = 4 \times T_{1/2} = 4 \times 6.0 = 24\ \mathrm{h}. $$

(A1)

无需对数,因为目标分数恰是 $\tfrac{1}{2}$ 的整数次幂,时间为整数倍半衰期。(R1)

要点。只要剩余分数为 $\tfrac{1}{2},\tfrac{1}{4},\tfrac{1}{8},\tfrac{1}{16},\dots$,最快的方法是数减半次数,而非动用指数定律。养成一眼把 $\tfrac{1}{16}$ 读作 $\left(\tfrac{1}{2}\right)^{4}$ 的习惯。E3.5 的指数定律只是最后手段,用于像 $0.30$ 这样落在两次减半之间的分数。
Q4HARDPaper 1activity, the becquerel, background活度、贝克勒尔、本底[6 marks]

$N = 8.0\times 10^{16}$, $\lambda = 3.0\times 10^{-9}\ \mathrm{s^{-1}}$. (a) activity, SI unit and meaning; (b) corrected count rate from $520\ \mathrm{s^{-1}}$ with $40\ \mathrm{s^{-1}}$ background; (c) two natural background sources and why decay is random and spontaneous.$N = 8.0\times 10^{16}$,$\lambda = 3.0\times 10^{-9}\ \mathrm{s^{-1}}$。(a) 活度、SI 单位及含义;(b) 由 $520\ \mathrm{s^{-1}}$、本底 $40\ \mathrm{s^{-1}}$ 求修正后计数率;(c) 两个天然本底来源及衰变为何随机且自发。

Answers:答案:  (a) $A = 2.4\times 10^{8}\ \mathrm{Bq}$; $1\ \mathrm{Bq} = 1$ decay per second  ·  (b) $480\ \mathrm{s^{-1}}$  ·  (c) e.g. radon, rocks/soil, cosmic rays; random and spontaneous as explained

(a) Activity, unit and meaning M1·A1·B1

Use the data-booklet relation $A = \lambda N$: $A = (3.0\times 10^{-9})(8.0\times 10^{16})$. (M1)

$$ A = 2.4\times 10^{8}\ \mathrm{Bq}. $$

(A1)

The SI unit of activity is the becquerel: $1\ \mathrm{Bq} = 1$ decay (disintegration) per second $= 1\ \mathrm{s^{-1}}$. (B1)

(b) Corrected count rate A1

Subtract the background from the measured rate: $520 - 40 = 480\ \mathrm{s^{-1}}$. (A1)

(c) Background sources; random and spontaneous B1·B1

Two natural sources of background radiation: radon gas, rocks and soil, cosmic rays, or radioactive isotopes in food and the body (any two). (B1)

Decay is random because it is impossible to predict which nucleus will decay or when (only the probability per unit time is fixed), and spontaneous because the decay rate is unaffected by temperature, pressure or chemical state. (B1)

Insight. Keep the three rates conceptually separate. The activity $A = \lambda N$ is the true number of decays per second inside the sample; the measured count rate is smaller because a detector only intercepts a fraction of the emissions; and the corrected count rate is the measured value minus the ever-present background. Confusing activity with count rate, or forgetting the background subtraction, is the classic way to lose easy marks in this topic.

(a) 活度、单位与含义 M1·A1·B1

用数据手册关系 $A = \lambda N$:$A = (3.0\times 10^{-9})(8.0\times 10^{16})$。(M1)

$$ A = 2.4\times 10^{8}\ \mathrm{Bq}. $$

(A1)

活度的 SI 单位是贝克勒尔:$1\ \mathrm{Bq} = $ 每秒 1 次衰变 $= 1\ \mathrm{s^{-1}}$。(B1)

(b) 修正后计数率 A1

从测得计数率减去本底:$520 - 40 = 480\ \mathrm{s^{-1}}$。(A1)

(c) 本底来源;随机与自发 B1·B1

本底辐射的两个天然来源:氡气、岩石与土壤、宇宙射线,或食物与人体中的放射性同位素(任两个)。(B1)

衰变是随机的,因为无法预测哪个核会衰变、何时衰变(只有每单位时间的概率固定);是自发的,因为衰变速率不受温度、压强或化学状态影响。(B1)

要点。把三种速率在概念上分清。活度 $A = \lambda N$ 是样品内部每秒真实衰变数;测得计数率更小,因为探测器只截获一部分发射;修正后计数率是测得值减去始终存在的本底。把活度与计数率混淆,或忘记扣除本底,是本专题丢掉送分题的典型方式。
Q5HARDPaper 1HL ONLYexponential law + decay constant指数定律与衰变常数[8 marks]

$T_{1/2} = 15\ \mathrm{h}$, $N_0 = 5.0\times 10^{18}$, $\ln 2 = 0.693$. (a) why $N = N_0 e^{-\lambda t}$; (b) $\lambda$ in $\mathrm{s^{-1}}$; (c) fraction undecayed after $24\ \mathrm{h}$; (d) initial activity in Bq.$T_{1/2} = 15\ \mathrm{h}$,$N_0 = 5.0\times 10^{18}$,$\ln 2 = 0.693$。(a) 为何 $N = N_0 e^{-\lambda t}$;(b) $\lambda$($\mathrm{s^{-1}}$);(c) $24\ \mathrm{h}$ 后未衰变分数;(d) 初始活度(Bq)。

Answers:答案:  (a) rate of decay $\propto N$  ·  (b) $\lambda \approx 1.28\times 10^{-5}\ \mathrm{s^{-1}}$  ·  (c) $\approx 0.33$  ·  (d) $A_0 \approx 6.4\times 10^{13}\ \mathrm{Bq}$

(a) Why decay is exponential M1·A1

Each nucleus has a constant probability $\lambda$ of decaying per unit time, so the number decaying per second is proportional to the number remaining: $\dfrac{dN}{dt} = -\lambda N$. (M1)

A quantity whose rate of change is proportional to itself decays exponentially, giving $N = N_0 e^{-\lambda t}$. (A1)

(b) Decay constant M1·A1

Use $\lambda = \dfrac{\ln 2}{T_{1/2}}$ with the half-life in seconds: $T_{1/2} = 15 \times 3600 = 5.4\times 10^{4}\ \mathrm{s}$. (M1)

$$ \lambda = \frac{0.693}{5.4\times 10^{4}} \approx 1.28\times 10^{-5}\ \mathrm{s^{-1}}. $$

(A1)

(c) Fraction undecayed after 24 hours M1·A1

Work in hours, where $\lambda_{\mathrm{h}} = \dfrac{0.693}{15} = 0.0462\ \mathrm{h^{-1}}$. Then $\dfrac{N}{N_0} = e^{-\lambda_{\mathrm{h}} t} = e^{-(0.0462)(24)} = e^{-1.109}$. (M1)

$$ \frac{N}{N_0} = e^{-1.109} \approx 0.33. $$

(A1)

(d) Initial activity M1·A1

Use $A_0 = \lambda N_0$ with $\lambda$ in $\mathrm{s^{-1}}$: $A_0 = (1.28\times 10^{-5})(5.0\times 10^{18})$. (M1)

$$ A_0 \approx 6.4\times 10^{13}\ \mathrm{Bq}. $$

(A1)

Insight. The unit trap dominates this question. For an activity in becquerels (decays per second) the decay constant must be in $\mathrm{s^{-1}}$, so the half-life is converted to seconds in (b) and (d). Part (c), by contrast, only needs a ratio, so any consistent time unit works and hours keep the arithmetic clean. A quick sanity check: $24\ \mathrm{h}$ is $1.6$ half-lives, between $\tfrac{1}{2}$ and $\tfrac{1}{4}$, consistent with $0.33$.

(a) 为何衰变是指数式 M1·A1

每个核每单位时间有恒定衰变概率 $\lambda$,故每秒衰变数正比于剩余数:$\dfrac{dN}{dt} = -\lambda N$。(M1)

变化率正比于自身的量呈指数衰减,得 $N = N_0 e^{-\lambda t}$。(A1)

(b) 衰变常数 M1·A1

用 $\lambda = \dfrac{\ln 2}{T_{1/2}}$,半衰期取秒:$T_{1/2} = 15 \times 3600 = 5.4\times 10^{4}\ \mathrm{s}$。(M1)

$$ \lambda = \frac{0.693}{5.4\times 10^{4}} \approx 1.28\times 10^{-5}\ \mathrm{s^{-1}}. $$

(A1)

(c) 24 小时后未衰变分数 M1·A1

以小时计算,$\lambda_{\mathrm{h}} = \dfrac{0.693}{15} = 0.0462\ \mathrm{h^{-1}}$。则 $\dfrac{N}{N_0} = e^{-\lambda_{\mathrm{h}} t} = e^{-(0.0462)(24)} = e^{-1.109}$。(M1)

$$ \frac{N}{N_0} = e^{-1.109} \approx 0.33. $$

(A1)

(d) 初始活度 M1·A1

用 $A_0 = \lambda N_0$,$\lambda$ 取 $\mathrm{s^{-1}}$:$A_0 = (1.28\times 10^{-5})(5.0\times 10^{18})$。(M1)

$$ A_0 \approx 6.4\times 10^{13}\ \mathrm{Bq}. $$

(A1)

要点。本题以单位陷阱为主。活度以贝克勒尔(每秒衰变数)表示时,衰变常数须为 $\mathrm{s^{-1}}$,故 (b) 与 (d) 把半衰期换算成秒。而 (c) 只需比值,任何一致的时间单位都可,用小时能让运算更简洁。快速验算:$24\ \mathrm{h}$ 约 $1.6$ 个半衰期,介于 $\tfrac{1}{2}$ 与 $\tfrac{1}{4}$ 之间,与 $0.33$ 一致。
PART II  ·  PAPER 1B / DATA ANALYSIS第二部分  ·  第一卷 B / 数据分析Graphs · data · uncertainties · 22 marks图像 · 数据 · 不确定度 · 22 分

Worked Solutions详细解析

Q6HARDPaper 1Bbackground subtraction + half-life from a decay curve本底扣除与由衰变曲线求半衰期[10 marks]

$C_{\text{meas}} = 340,180,100,60\ \mathrm{s^{-1}}$ at $t = 0,10,20,30\ \mathrm{min}$; background $20\ \mathrm{s^{-1}}$. (a) why subtract, and the corrected rates; (b) half-life from the halvings; (c) percentage uncertainty at $t = 30\ \mathrm{min}$ given $\pm 10\ \mathrm{s^{-1}}$; (d) relation between count-rate half-life and nuclei half-life.$t = 0,10,20,30\ \mathrm{min}$ 时 $C_{\text{meas}} = 340,180,100,60\ \mathrm{s^{-1}}$;本底 $20\ \mathrm{s^{-1}}$。(a) 为何扣除及修正后速率;(b) 由减半求半衰期;(c) 给定 $\pm 10\ \mathrm{s^{-1}}$ 时 $t = 30\ \mathrm{min}$ 处的百分比不确定度;(d) 计数率半衰期与核数半衰期的关系。

Answers:答案:  (a) corrected $= 320,160,80,40\ \mathrm{s^{-1}}$  ·  (b) $T_{1/2} = 10\ \mathrm{min}$  ·  (c) $\approx 25\%$  ·  (d) the same half-life

(a) Subtracting the background R1·M1·A1

The background is present whether or not the source is there, so it must be removed to leave the true count rate due to the source alone; otherwise the curve would level off at the background instead of tending to zero. (R1)

Subtract $20\ \mathrm{s^{-1}}$ from each reading: (M1)

$$ 340-20,\ 180-20,\ 100-20,\ 60-20 = 320,\ 160,\ 80,\ 40\ \mathrm{s^{-1}}. $$

(A1)

(b) Half-life from halvings M1·A1·A1

The corrected rate halves at each step: $320 \to 160 \to 80 \to 40$, which is $3$ halvings over the $30\ \mathrm{min}$ recorded. (M1)

So $3\,T_{1/2} = 30\ \mathrm{min}$ (A1), giving $T_{1/2} = 10\ \mathrm{min}$. (A1)

(c) Percentage uncertainty at $t = 30\ \mathrm{min}$ M1·A1

The corrected count rate there is $40\ \mathrm{s^{-1}}$, with absolute uncertainty $\pm 10\ \mathrm{s^{-1}}$ (background uncertainty negligible): (M1)

$$ \frac{10}{40}\times 100\% = 25\%. $$

(A1)

(d) Count-rate vs nuclei half-life A1·R1

The half-life of the count rate equals the half-life of the number of undecayed nuclei. (A1)

Because the count rate is proportional to the activity and $A = \lambda N$ with $\lambda$ constant, the count rate is proportional to $N$ at all times, so the two share the same half-life. (R1)

Insight. The percentage uncertainty climbing to $25\%$ at the last point is the real lesson: as the corrected rate falls toward the background, a fixed absolute uncertainty becomes a large fractional one, so late readings are the least reliable. This is exactly why count-rate measurements are taken before the source decays too far, and why background subtraction must come first; subtracting it after fitting would corrupt the apparent half-life.

(a) 扣除本底 R1·M1·A1

无论源是否在场,本底都存在,故须扣除以留下仅由源贡献的真实计数率;否则曲线会在本底处趋平,而非趋于零。(R1)

从每个读数减去 $20\ \mathrm{s^{-1}}$:(M1)

$$ 340-20,\ 180-20,\ 100-20,\ 60-20 = 320,\ 160,\ 80,\ 40\ \mathrm{s^{-1}}. $$

(A1)

(b) 由减半求半衰期 M1·A1·A1

修正后速率每步减半:$320 \to 160 \to 80 \to 40$,即在记录的 $30\ \mathrm{min}$ 内减半 $3$ 次。(M1)

故 $3\,T_{1/2} = 30\ \mathrm{min}$(A1),得 $T_{1/2} = 10\ \mathrm{min}$。(A1)

(c) $t = 30\ \mathrm{min}$ 处的百分比不确定度 M1·A1

该处修正后计数率为 $40\ \mathrm{s^{-1}}$,绝对不确定度 $\pm 10\ \mathrm{s^{-1}}$(本底不确定度可忽略):(M1)

$$ \frac{10}{40}\times 100\% = 25\%. $$

(A1)

(d) 计数率与核数半衰期 A1·R1

计数率的半衰期等于未衰变核数的半衰期。(A1)

因为计数率正比于活度,而 $A = \lambda N$ 且 $\lambda$ 恒定,故计数率在任一时刻都正比于 $N$,二者半衰期相同。(R1)

要点。最后一点的百分比不确定度升至 $25\%$ 才是真正的教训:当修正后速率趋近本底时,固定的绝对不确定度变成很大的相对不确定度,故后期读数最不可靠。这正是要在源衰变过头之前测计数率、并须先扣除本底的原因;拟合后再扣会污染表观半衰期。
Q7HARDPaper 1BHL ONLYlinearising the decay law: $\ln C$ vs $t$衰变定律线性化:$\ln C$ 对 $t$[12 marks]

Corrected $C = 1000,779,607,472,368\ \mathrm{s^{-1}}$ at $t = 0,10,20,30,40\ \mathrm{s}$. (a) show $\ln C$ vs $t$ is linear, gradient and intercept; (b) tabulate $\ln C$, find the gradient and $\lambda$; (c) half-life; (d) intercept and $C_0$; (e) one advantage of the log plot.$t = 0,10,20,30,40\ \mathrm{s}$ 时修正后 $C = 1000,779,607,472,368\ \mathrm{s^{-1}}$。(a) 证明 $\ln C$ 对 $t$ 为直线、斜率与截距;(b) 列 $\ln C$ 表、求斜率与 $\lambda$;(c) 半衰期;(d) 截距与 $C_0$;(e) 对数图的一个优点。

Answers:答案:  (a) $\ln C = \ln C_0 - \lambda t$  ·  (b) gradient $= -0.025\ \mathrm{s^{-1}}$, $\lambda = 0.025\ \mathrm{s^{-1}}$  ·  (c) $T_{1/2} \approx 28\ \mathrm{s}$  ·  (d) intercept $\approx 6.91$, $C_0 \approx 1000\ \mathrm{s^{-1}}$

(a) Why $\ln C$ vs $t$ is a straight line M1·A1·A1

Take natural logs of $C = C_0 e^{-\lambda t}$: (M1)

$$ \ln C = \ln C_0 - \lambda t. $$

This has the form $y = c + mx$ with $y = \ln C$ and $x = t$, so a plot of $\ln C$ against $t$ is a straight line. (A1)

The gradient is $-\lambda$ and the vertical intercept is $\ln C_0$. (A1)

(b) Table, gradient and decay constant M1·A1·A1

Computing $\ln C$ for each reading: (M1)

$t\ /\ \mathrm{s}$$0$$10$$20$$30$$40$
$\ln C$$6.908$$6.658$$6.409$$6.157$$5.908$

The $\ln C$ values fall by about $0.25$ every $10\ \mathrm{s}$. Using the endpoints: (A1)

$$ \text{gradient} = \frac{5.908 - 6.908}{40 - 0} = \frac{-1.000}{40} = -0.025\ \mathrm{s^{-1}}. $$

Since the gradient is $-\lambda$, the decay constant is $\lambda = 0.025\ \mathrm{s^{-1}}$. (A1)

(c) Half-life M1·A1

Use $T_{1/2} = \dfrac{\ln 2}{\lambda} = \dfrac{0.693}{0.025}$: (M1)

$$ T_{1/2} = 27.7 \approx 28\ \mathrm{s}. $$

(A1)

(d) Intercept and initial count rate A1·A1

The vertical intercept is $\ln C_0 = 6.908$. (A1)

Hence $C_0 = e^{6.908} \approx 1.0\times 10^{3}\ \mathrm{s^{-1}}$, which matches the $t = 0$ reading of $1000\ \mathrm{s^{-1}}$. (A1)

(e) Advantage of the log plot B1·R1

Plotting $\ln C$ against $t$ gives a straight line whose gradient uses every data point through a best-fit, rather than relying on a single halving read off a curve. (B1)

A straight-line fit averages out random scatter and makes any departure from exponential decay (curvature) immediately visible, so $\lambda$ is obtained more reliably. (R1)

Insight. Linearising is the signature Paper 1B skill: rearrange the relationship so the unknown sits in the gradient of a straight line. For exponential decay the move is always "take logs", turning $C = C_0 e^{-\lambda t}$ into $\ln C = \ln C_0 - \lambda t$. Watch the sign, the gradient is $-\lambda$ not $\lambda$, and read the gradient from the line or widely spaced points, never by dividing a single $(t,\ln C)$ pair.

(a) 为何 $\ln C$ 对 $t$ 为直线 M1·A1·A1

对 $C = C_0 e^{-\lambda t}$ 取自然对数:(M1)

$$ \ln C = \ln C_0 - \lambda t. $$

此式形如 $y = c + mx$,其中 $y = \ln C$、$x = t$,故 $\ln C$ 对 $t$ 作图为直线。(A1)

斜率为 $-\lambda$,纵截距为 $\ln C_0$。(A1)

(b) 表、斜率与衰变常数 M1·A1·A1

对每个读数计算 $\ln C$:(M1)

$t\ /\ \mathrm{s}$$0$$10$$20$$30$$40$
$\ln C$$6.908$$6.658$$6.409$$6.157$$5.908$

$\ln C$ 值每 $10\ \mathrm{s}$ 约下降 $0.25$。用两端点:(A1)

$$ \text{斜率} = \frac{5.908 - 6.908}{40 - 0} = \frac{-1.000}{40} = -0.025\ \mathrm{s^{-1}}. $$

因斜率为 $-\lambda$,衰变常数 $\lambda = 0.025\ \mathrm{s^{-1}}$。(A1)

(c) 半衰期 M1·A1

用 $T_{1/2} = \dfrac{\ln 2}{\lambda} = \dfrac{0.693}{0.025}$:(M1)

$$ T_{1/2} = 27.7 \approx 28\ \mathrm{s}. $$

(A1)

(d) 截距与初始计数率 A1·A1

纵截距为 $\ln C_0 = 6.908$。(A1)

故 $C_0 = e^{6.908} \approx 1.0\times 10^{3}\ \mathrm{s^{-1}}$,与 $t = 0$ 读数 $1000\ \mathrm{s^{-1}}$ 一致。(A1)

(e) 对数图的优点 B1·R1

绘制 $\ln C$ 对 $t$ 得到直线,其斜率经最佳拟合用上每个数据点,而非依赖从曲线上读出的单次减半。(B1)

直线拟合平均掉随机散布,并使任何偏离指数衰变(弯曲)立即可见,故 $\lambda$ 求得更可靠。(R1)

要点。线性化是 Paper 1B 的标志技能:重排关系,使未知量落在直线斜率上。对指数衰变,做法永远是"取对数",把 $C = C_0 e^{-\lambda t}$ 化为 $\ln C = \ln C_0 - \lambda t$。注意符号,斜率是 $-\lambda$ 而非 $\lambda$,并从直线或相距较远的点读斜率,绝不用单个 $(t,\ln C)$ 相除。
PART III  ·  PAPER 2 STYLE第三部分  ·  第二卷风格Extended structured · 30 marks长结构题 · 30 分

Worked Solutions详细解析

Q8HARDPaper 2HL ONLYcarbon dating with the exponential law用指数定律进行碳测年[12 marks]

${}^{14}\mathrm{C}$, $T_{1/2} = 5\,730\ \mathrm{yr}$, $\ln 2 = 0.693$; tool activity is $30\%$ of living wood. (a) the beta-minus equation to nitrogen; (b) $\lambda$ in $\mathrm{yr^{-1}}$; (c) age by taking logs; (d) why the age is between one and two half-lives; (e) why dating fails for very old samples.${}^{14}\mathrm{C}$,$T_{1/2} = 5\,730\ \mathrm{yr}$,$\ln 2 = 0.693$;工具活度为活木的 $30\%$。(a) 到氮的 β⁻ 方程;(b) $\lambda$($\mathrm{yr^{-1}}$);(c) 取对数求年代;(d) 为何年代介于一与两个半衰期之间;(e) 为何对很老样品失效。

Answers:答案:  (a) ${}^{14}_{6}\mathrm{C} \to {}^{14}_{7}\mathrm{N} + {}^{0}_{-1}\beta + \bar{\nu}_e$  ·  (b) $\lambda \approx 1.21\times 10^{-4}\ \mathrm{yr^{-1}}$  ·  (c) age $\approx 9\,950\ \mathrm{yr}$  ·  (d) $0.30$ lies between $0.50$ and $0.25$

(a) Beta-minus equation M1·A1

Beta-minus keeps $A = 14$ and raises $Z$ from $6$ to $7$ (nitrogen), with an electron and an antineutrino emitted: (M1)

$$ {}^{14}_{6}\mathrm{C} \to {}^{14}_{7}\mathrm{N} + {}^{0}_{-1}\beta + \bar{\nu}_e. $$

(A1)

(b) Decay constant M1·A1

$\lambda = \dfrac{\ln 2}{T_{1/2}} = \dfrac{0.693}{5730}$: (M1)

$$ \lambda \approx 1.21\times 10^{-4}\ \mathrm{yr^{-1}}. $$

(A1)

(c) Age of the tool M1·M1·A1·A1

The activity is proportional to the number of ${}^{14}\mathrm{C}$ nuclei, so $\dfrac{A}{A_0} = e^{-\lambda t} = 0.30$. Take natural logs: (M1)

$$ -\lambda t = \ln(0.30) \;\Rightarrow\; t = \frac{1}{\lambda}\ln\!\frac{1}{0.30} = \frac{\ln(0.30)}{-\lambda}. $$

(M1 for rearranging to $t$)

$$ t = \frac{1.204}{1.21\times 10^{-4}}. $$

(A1)

$$ t \approx 9\,950\ \mathrm{yr} \;(\approx 9.9\times 10^{3}\ \mathrm{yr}). $$

(A1)

(d) Bracketing check R1·A1

One half-life leaves $50\%$ ($5\,730\ \mathrm{yr}$) and two half-lives leave $25\%$ ($11\,460\ \mathrm{yr}$). Since $30\%$ lies between $50\%$ and $25\%$, the age must lie between one and two half-lives. (R1)

The computed $9\,950\ \mathrm{yr}$ sits between $5\,730$ and $11\,460\ \mathrm{yr}$, confirming the answer. (A1)

(e) Why dating fails for very old samples B1·R1

After many half-lives the remaining ${}^{14}\mathrm{C}$ activity becomes very small, comparable with the background. (B1)

The corrected count rate is then dominated by uncertainty, so the measured fraction (and hence the age) cannot be determined reliably. (R1)

Insight. Carbon dating is the canonical exponential-law problem because the fraction $0.30$ is not a power of $\tfrac{1}{2}$, forcing the logarithm. The marker rewards the explicit log step $t = \tfrac{1}{\lambda}\ln(A_0/A)$ and a final value to sensible figures. The bracketing argument in (d) is the cheap insurance every candidate should run: if the answer fell outside one-to-two half-lives for a $30\%$ reading, an arithmetic slip would be exposed at once.

(a) β⁻ 方程 M1·A1

β⁻ 使 $A = 14$ 不变、$Z$ 从 $6$ 增到 $7$(氮),并发射一个电子与一个反中微子:(M1)

$$ {}^{14}_{6}\mathrm{C} \to {}^{14}_{7}\mathrm{N} + {}^{0}_{-1}\beta + \bar{\nu}_e. $$

(A1)

(b) 衰变常数 M1·A1

$\lambda = \dfrac{\ln 2}{T_{1/2}} = \dfrac{0.693}{5730}$:(M1)

$$ \lambda \approx 1.21\times 10^{-4}\ \mathrm{yr^{-1}}. $$

(A1)

(c) 工具年代 M1·M1·A1·A1

活度正比于 ${}^{14}\mathrm{C}$ 核数,故 $\dfrac{A}{A_0} = e^{-\lambda t} = 0.30$。取自然对数:(M1)

$$ -\lambda t = \ln(0.30) \;\Rightarrow\; t = \frac{1}{\lambda}\ln\!\frac{1}{0.30} = \frac{\ln(0.30)}{-\lambda}. $$

(整理为 $t$ 得 M1)

$$ t = \frac{1.204}{1.21\times 10^{-4}}. $$

(A1)

$$ t \approx 9\,950\ \mathrm{yr} \;(\approx 9.9\times 10^{3}\ \mathrm{yr}). $$

(A1)

(d) 区间核对 R1·A1

一个半衰期剩 $50\%$($5\,730\ \mathrm{yr}$),两个半衰期剩 $25\%$($11\,460\ \mathrm{yr}$)。因 $30\%$ 介于 $50\%$ 与 $25\%$ 之间,年代须介于一与两个半衰期之间。(R1)

所求 $9\,950\ \mathrm{yr}$ 落在 $5\,730$ 与 $11\,460\ \mathrm{yr}$ 之间,验证了答案。(A1)

(e) 为何对很老样品失效 B1·R1

经过许多半衰期后,剩余 ${}^{14}\mathrm{C}$ 活度变得很小,与本底相当。(B1)

此时修正后计数率被不确定度主导,故测得分数(进而年代)无法可靠确定。(R1)

要点。碳测年是指数定律的范式题,因为分数 $0.30$ 不是 $\tfrac{1}{2}$ 的幂,必须用对数。阅卷奖励明确的取对数步骤 $t = \tfrac{1}{\lambda}\ln(A_0/A)$ 与取合理有效数字的最终值。(d) 的区间论证是每位考生都应做的廉价保险:若 $30\%$ 读数的答案落在一到两个半衰期之外,算术失误会立即暴露。
Q9HARDPaper 2medical isotope: activity over several half-lives医用同位素:跨多个半衰期的活度[10 marks]

Medical isotope, $T_{1/2} = 6.0\ \mathrm{h}$, $A_0 = 4.0\times 10^{10}\ \mathrm{Bq}$ at arrival. (a) meaning of the activity; (b) activity after $24\ \mathrm{h}$; (c) time to fall to $5.0\times 10^{9}\ \mathrm{Bq}$; (d) why use promptly, given a $1.0\times 10^{10}\ \mathrm{Bq}$ threshold.医用同位素,$T_{1/2} = 6.0\ \mathrm{h}$,到货时 $A_0 = 4.0\times 10^{10}\ \mathrm{Bq}$。(a) 活度含义;(b) $24\ \mathrm{h}$ 后活度;(c) 降到 $5.0\times 10^{9}\ \mathrm{Bq}$ 的时间;(d) 给定 $1.0\times 10^{10}\ \mathrm{Bq}$ 阈值,为何尽快使用。

Answers:答案:  (a) $4.0\times 10^{10}$ decays per second  ·  (b) $2.5\times 10^{9}\ \mathrm{Bq}$  ·  (c) $18\ \mathrm{h}$  ·  (d) threshold reached at $12\ \mathrm{h}$, so use within $12\ \mathrm{h}$

(a) Meaning of the activity B1

An activity of $4.0\times 10^{10}\ \mathrm{Bq}$ means $4.0\times 10^{10}$ nuclei decay per second in the sample ($1\ \mathrm{Bq} = 1$ decay per second). (B1)

(b) Activity after 24 hours M1·M1·A1

Number of half-lives: $n = \dfrac{24}{6.0} = 4$. (M1)

The activity falls by $\left(\tfrac{1}{2}\right)^{4} = \tfrac{1}{16}$: (M1)

$$ A = \frac{4.0\times 10^{10}}{16} = 2.5\times 10^{9}\ \mathrm{Bq}. $$

(A1)

(c) Time to fall to $5.0\times 10^{9}\ \mathrm{Bq}$ M1·M1·A1

The ratio is $\dfrac{5.0\times 10^{9}}{4.0\times 10^{10}} = \dfrac{1}{8} = \left(\tfrac{1}{2}\right)^{3}$, so $3$ half-lives have passed. (M1·M1)

$$ t = 3 \times 6.0 = 18\ \mathrm{h}. $$

(A1)

(d) Why use promptly M1·A1·R1

The threshold ratio is $\dfrac{1.0\times 10^{10}}{4.0\times 10^{10}} = \dfrac{1}{4} = \left(\tfrac{1}{2}\right)^{2}$, which is reached after $2$ half-lives, i.e. $t = 12\ \mathrm{h}$. (M1·A1)

Because $A = \lambda N$ with $\lambda$ fixed, the activity falls as the number of undecayed nuclei falls; after $12\ \mathrm{h}$ too few nuclei remain to meet the required activity, so the isotope must be used within about $12\ \mathrm{h}$ of arrival. (R1)

Insight. Every part here is a whole number of half-lives, so the fraction rule beats the exponential law on speed and accuracy; spotting $\tfrac{1}{16}, \tfrac{1}{8}, \tfrac{1}{4}$ as powers of $\tfrac{1}{2}$ is the entire trick. The link $A = \lambda N$ is what makes the activity itself decay with the same half-life as the nuclei, which is why a short-lived isotope is most useful immediately on delivery and is the reason hospitals schedule scans around isotope arrival times.

(a) 活度的含义 B1

$4.0\times 10^{10}\ \mathrm{Bq}$ 的活度表示样品中每秒有 $4.0\times 10^{10}$ 个核衰变($1\ \mathrm{Bq} = $ 每秒 1 次衰变)。(B1)

(b) 24 小时后的活度 M1·M1·A1

半衰期个数:$n = \dfrac{24}{6.0} = 4$。(M1)

活度降为 $\left(\tfrac{1}{2}\right)^{4} = \tfrac{1}{16}$:(M1)

$$ A = \frac{4.0\times 10^{10}}{16} = 2.5\times 10^{9}\ \mathrm{Bq}. $$

(A1)

(c) 降到 $5.0\times 10^{9}\ \mathrm{Bq}$ 的时间 M1·M1·A1

比值为 $\dfrac{5.0\times 10^{9}}{4.0\times 10^{10}} = \dfrac{1}{8} = \left(\tfrac{1}{2}\right)^{3}$,故已过 $3$ 个半衰期。(M1·M1)

$$ t = 3 \times 6.0 = 18\ \mathrm{h}. $$

(A1)

(d) 为何尽快使用 M1·A1·R1

阈值比为 $\dfrac{1.0\times 10^{10}}{4.0\times 10^{10}} = \dfrac{1}{4} = \left(\tfrac{1}{2}\right)^{2}$,在 $2$ 个半衰期后到达,即 $t = 12\ \mathrm{h}$。(M1·A1)

因 $A = \lambda N$ 且 $\lambda$ 固定,活度随未衰变核数减少而下降;$12\ \mathrm{h}$ 后剩余核太少,无法满足所需活度,故同位素须在到货后约 $12\ \mathrm{h}$ 内使用。(R1)

要点。这里每一问都是整数倍半衰期,故分数法则在速度与准确度上都胜过指数定律;把 $\tfrac{1}{16}, \tfrac{1}{8}, \tfrac{1}{4}$ 识别为 $\tfrac{1}{2}$ 的幂就是全部诀窍。关系 $A = \lambda N$ 使活度本身与核数以相同半衰期衰减,这正是短寿命同位素到货即用最有价值的原因,也是医院围绕同位素到货时间安排扫描的原因。
Q10HARDPaper 2HL ONLYalpha emitter: equation, activity, decay over timeα 发射体:方程、活度、随时间衰变[8 marks]

${}^{210}_{84}\mathrm{Po}$, alpha emitter, $T_{1/2} = 138\ \mathrm{days}$, decays to Pb $(Z = 82)$; $N_0 = 2.0\times 10^{20}$, $\ln 2 = 0.693$. (a) decay equation; (b) absorber that stops the alpha with reason; (c) $\lambda$ in $\mathrm{s^{-1}}$ and initial activity; (d) activity after $276\ \mathrm{days}$.${}^{210}_{84}\mathrm{Po}$,α 发射体,$T_{1/2} = 138\ \mathrm{天}$,衰变为铅 $(Z = 82)$;$N_0 = 2.0\times 10^{20}$,$\ln 2 = 0.693$。(a) 衰变方程;(b) 挡住 α 的吸收体及理由;(c) $\lambda$($\mathrm{s^{-1}}$)与初始活度;(d) $276\ \mathrm{天}$ 后活度。

Answers:答案:  (a) ${}^{210}_{84}\mathrm{Po} \to {}^{206}_{82}\mathrm{Pb} + {}^{4}_{2}\alpha$  ·  (b) a sheet of paper (or a few cm of air)  ·  (c) $\lambda \approx 5.8\times 10^{-8}\ \mathrm{s^{-1}}$, $A_0 \approx 1.2\times 10^{13}\ \mathrm{Bq}$  ·  (d) $A \approx 2.9\times 10^{12}\ \mathrm{Bq}$

(a) Decay equation M1·A1

Alpha emission removes $4$ from $A$ and $2$ from $Z$: $A = 210 - 4 = 206$, $Z = 84 - 2 = 82$ (lead). (M1)

$$ {}^{210}_{84}\mathrm{Po} \to {}^{206}_{82}\mathrm{Pb} + {}^{4}_{2}\alpha. $$

The lead isotope produced is ${}^{206}_{82}\mathrm{Pb}$. (A1)

(b) Stopping the alpha A1·R1

A single sheet of paper (or a few centimetres of air) is sufficient to stop the alpha radiation. (A1)

Alpha particles are heavy and doubly charged, so they ionise strongly and lose their energy over a very short range, making them the least penetrating of the three radiations. (R1)

(c) Decay constant and initial activity M1·M1·A1

Convert the half-life to seconds: $T_{1/2} = 138 \times 86400 = 1.19\times 10^{7}\ \mathrm{s}$, then $\lambda = \dfrac{\ln 2}{T_{1/2}}$: (M1)

$$ \lambda = \frac{0.693}{1.19\times 10^{7}} \approx 5.8\times 10^{-8}\ \mathrm{s^{-1}}. $$

Use $A_0 = \lambda N_0 = (5.8\times 10^{-8})(2.0\times 10^{20})$: (M1)

$$ A_0 \approx 1.2\times 10^{13}\ \mathrm{Bq}. $$

(A1)

(d) Activity after 276 days A1

$276\ \mathrm{days} = 2\,T_{1/2}$, so the activity falls to $\left(\tfrac{1}{2}\right)^{2} = \tfrac{1}{4}$ of $A_0$: $A = \dfrac{1.2\times 10^{13}}{4} \approx 2.9\times 10^{12}\ \mathrm{Bq}$. (A1)

Insight. This question stitches the whole unit together: balance an alpha equation, recall that alpha is the least penetrating radiation, convert a half-life to $\mathrm{s^{-1}}$ for an activity in becquerels, and then exploit a whole-number-of-half-lives shortcut for the final step. The deliberate mix of methods is typical of Paper 2; the single most common slip is leaving $\lambda$ in $\mathrm{day^{-1}}$ while quoting the activity in $\mathrm{Bq}$, which is off by a factor of $86\,400$.

(a) 衰变方程 M1·A1

α 发射使 $A$ 减 $4$、$Z$ 减 $2$:$A = 210 - 4 = 206$,$Z = 84 - 2 = 82$(铅)。(M1)

$$ {}^{210}_{84}\mathrm{Po} \to {}^{206}_{82}\mathrm{Pb} + {}^{4}_{2}\alpha. $$

生成的铅同位素为 ${}^{206}_{82}\mathrm{Pb}$。(A1)

(b) 挡住 α A1·R1

一张纸(或几厘米空气)即足以挡住 α 辐射。(A1)

α 粒子重且带两个正电荷,电离强,能量在极短程内损失殆尽,故是三种辐射中穿透力最弱的。(R1)

(c) 衰变常数与初始活度 M1·M1·A1

把半衰期换成秒:$T_{1/2} = 138 \times 86400 = 1.19\times 10^{7}\ \mathrm{s}$,再 $\lambda = \dfrac{\ln 2}{T_{1/2}}$:(M1)

$$ \lambda = \frac{0.693}{1.19\times 10^{7}} \approx 5.8\times 10^{-8}\ \mathrm{s^{-1}}. $$

用 $A_0 = \lambda N_0 = (5.8\times 10^{-8})(2.0\times 10^{20})$:(M1)

$$ A_0 \approx 1.2\times 10^{13}\ \mathrm{Bq}. $$

(A1)

(d) 276 天后的活度 A1

$276\ \mathrm{天} = 2\,T_{1/2}$,故活度降为 $A_0$ 的 $\left(\tfrac{1}{2}\right)^{2} = \tfrac{1}{4}$:$A = \dfrac{1.2\times 10^{13}}{4} \approx 2.9\times 10^{12}\ \mathrm{Bq}$。(A1)

要点。本题把整个单元串起来:配平 α 方程、记住 α 穿透力最弱、为求贝克勒尔活度把半衰期换成 $\mathrm{s^{-1}}$,最后一步再借整数倍半衰期的捷径。这种刻意的方法混合是 Paper 2 的典型;最常见的失误是把 $\lambda$ 留在 $\mathrm{day^{-1}}$ 却用 $\mathrm{Bq}$ 报活度,相差 $86\,400$ 倍。