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Unit B1 · SolutionsUnit B1 · 解析

Thermal Energy Transfers · Solutions热能传递 · 解析

Companion to the IB-Style Practice SetIB 风格练习题的解析配套

MEDIUM HARD Paper 1 Paper 1B Paper 2

Syllabus B1.1 to B1.6考纲 B1.1 至 B1.6PHYSICS HL



PART I  ·  PAPER 1 STYLE第一部分  ·  第一卷风格Short structured · 21 marks短结构题 · 21 分

Worked Solutions详细解析

Q1MEDIUMPaper 1temperature, internal energy, phase温度、内能与相态[4 marks]

Helium gas at $27\ ^{\circ}\mathrm{C}$. (a) convert to kelvin and state the effect of doubling absolute temperature on average molecular KE; (b) define internal energy and explain why warming raises it.氦气处于 $27\ ^{\circ}\mathrm{C}$。(a) 换算为开尔文,并说明绝对温度加倍对平均分子动能的影响;(b) 定义内能,并解释加热为何使其增大。

Answers:答案:  (a) $T = 300\ \mathrm{K}$; average KE doubles  ·  (b) $U = $ total molecular KE $+$ molecular PE; warming raises the KE term

(a) Kelvin conversion and the KE link A1·A1

Use $T(\mathrm{K}) = \theta(^{\circ}\mathrm{C}) + 273$: $T = 27 + 273 = 300\ \mathrm{K}$. (A1)

The average random kinetic energy of the molecules is directly proportional to the absolute temperature, so doubling $T$ (to $600\ \mathrm{K}$) doubles the average molecular kinetic energy. (A1)

(b) Internal energy and warming A1·A1

The internal energy $U$ is the total of the random kinetic energies of all the molecules plus the intermolecular potential energies: $U = \mathrm{KE}_{\text{molecular}} + \mathrm{PE}_{\text{molecular}}$. (A1)

Warming the gas with no phase change leaves the molecular PE unchanged but raises the molecular KE (the molecules move faster), so the internal energy increases through its kinetic part. (A1)

Insight. Two clean separations win the marks in B1.1: temperature tracks only the kinetic part of the internal energy, while the potential part tracks the phase. Because the link is to the absolute temperature, a doubling argument must use kelvin, never celsius. Note that the average KE doubles ($300 \to 600\ \mathrm{K}$), but the average molecular speed does not, since $\overline{E}_k \propto v^2$.

(a) 开尔文换算与动能关系 A1·A1

用 $T(\mathrm{K}) = \theta(^{\circ}\mathrm{C}) + 273$:$T = 27 + 273 = 300\ \mathrm{K}$。(A1)

分子的平均随机动能与绝对温度成正比,故 $T$ 加倍(至 $600\ \mathrm{K}$)使平均分子动能加倍。(A1)

(b) 内能与加热 A1·A1

内能 $U$ 是所有分子随机动能与分子间势能的总和:$U = \mathrm{KE}_{\text{molecular}} + \mathrm{PE}_{\text{molecular}}$。(A1)

无相变地加热气体时分子势能不变,但分子动能增大(分子运动更快),故内能通过其动能部分增大。(A1)

要点。B1.1 拿分靠两个清晰的分离:温度只反映内能的动能部分,而势能部分反映相态。由于关系系于绝对温度,加倍论证必须用开尔文,绝不能用摄氏。注意平均动能加倍($300 \to 600\ \mathrm{K}$),但平均分子速率并不加倍,因为 $\overline{E}_k \propto v^2$。
Q2MEDIUMPaper 1specific heat: electrical method比热容:电热法[5 marks]

$50\ \mathrm{W}$ heater in a $0.40\ \mathrm{kg}$ block; $90\ \mathrm{s}$ gives $\Delta T = 9.0\ \mathrm{K}$. (a) energy supplied and specific heat capacity; (b) over- or under-estimate when heat is lost, with justification.$50\ \mathrm{W}$ 加热器嵌入 $0.40\ \mathrm{kg}$ 金属块;$90\ \mathrm{s}$ 使 $\Delta T = 9.0\ \mathrm{K}$。(a) 供能与比热容;(b) 有热损失时偏大还是偏小,并说明理由。

Answers:答案:  (a) $Q = 4500\ \mathrm{J}$, $c = 1250\ \mathrm{J\,kg^{-1}\,K^{-1}}$  ·  (b) overestimate

(a) Energy supplied and specific heat capacity M1·M1·A1

The energy supplied is $Q = Pt = (50)(90) = 4500\ \mathrm{J}$. (M1)

Apply $Q = mc\Delta T$ and solve for $c$: (M1)

$$ c = \frac{Q}{m\,\Delta T} = \frac{4500}{(0.40)(9.0)} = 1250\ \mathrm{J\,kg^{-1}\,K^{-1}}. $$

(A1)

(b) Effect of heat loss A1·R1

If energy leaks to the surroundings, less than $4500\ \mathrm{J}$ actually goes into the block, yet the calculation assumes all of it does. (R1)

Dividing the full input energy by the measured $\Delta T$ therefore gives a value of $c$ that is too large, so the experimental value is an overestimate. (A1)

Insight. The electrical method rests on the bookkeeping identity $Pt = mc\Delta T$. To decide the direction of a systematic error, ask which term the loss corrupts: here the loss shrinks the energy that reaches the sample but leaves $\Delta T$ measured at face value, so the computed $c = Pt/(m\Delta T)$ comes out high. The standard fixes are lagging the block or extrapolating a temperature-time graph back to the point where losses are smallest.

(a) 供能与比热容 M1·M1·A1

供给的能量为 $Q = Pt = (50)(90) = 4500\ \mathrm{J}$。(M1)

用 $Q = mc\Delta T$ 解出 $c$:(M1)

$$ c = \frac{Q}{m\,\Delta T} = \frac{4500}{(0.40)(9.0)} = 1250\ \mathrm{J\,kg^{-1}\,K^{-1}}. $$

(A1)

(b) 热损失的影响 A1·R1

若能量泄漏到环境,实际进入金属块的能量不足 $4500\ \mathrm{J}$,而计算却假定全部进入。(R1)

用全部输入能量除以测得的 $\Delta T$,故得到的 $c$ 偏大,即实验值偏高。(A1)

要点。电热法依赖记账等式 $Pt = mc\Delta T$。判断系统误差方向时,要问损失破坏了哪一项:这里损失减少了到达样品的能量,却让 $\Delta T$ 按测得值原样使用,故算得的 $c = Pt/(m\Delta T)$ 偏高。标准修正是给金属块加隔热层,或把温度-时间图外推回损失最小的点。
Q3HARDPaper 1conduction, convection, radiation传导、对流、辐射[6 marks]

Vacuum flask: double wall with a vacuum gap, silvered surfaces. (a) why conduction and convection fail across the gap; (b) how silvering helps and which mechanism; (c) which mechanism crosses a vacuum.真空保温瓶:双层壁带真空间隙,表面镀银。(a) 为何传导与对流无法越过间隙;(b) 镀银如何帮助及涉及哪种机制;(c) 哪种机制能穿越真空。

Answers:答案:  (a) a vacuum has almost no particles, so neither conduction nor a convection current can form  ·  (b) silvering is a poor emitter / good reflector, cutting radiation  ·  (c) radiation

(a) Why conduction and convection fail M1·A1·A1

Conduction transfers energy by particle-to-particle interaction, and convection transfers energy by the bulk movement of a fluid; both require matter. (M1)

A vacuum contains almost no particles, so there is no chain of colliding particles to conduct energy across the gap. (A1)

With no fluid in the gap, no convection current of rising warm fluid and sinking cool fluid can form either. (A1)

(b) Role of the silvered surfaces A1·A1

The relevant mechanism is thermal radiation, which crosses the vacuum as electromagnetic (infrared) waves. (A1)

A shiny silvered surface has a low emissivity, so it is a poor emitter and a good reflector of infrared: it radiates little energy outward and reflects radiation back toward the drink, reducing radiative loss. (A1)

(c) Mechanism that crosses a vacuum B1

Radiation is the only mechanism that needs no medium and so can transfer energy through a vacuum. (B1)

Insight. The flask is the canonical exam vehicle because each design feature targets exactly one mechanism: the vacuum gap defeats the two matter-dependent mechanisms (conduction and convection) at once, while the silvering attacks the one mechanism that needs no medium (radiation). State the mechanism by name before describing the feature, because the marks are tied to the mechanism, not the gadget.

(a) 为何传导与对流失效 M1·A1·A1

热传导靠粒子间相互作用传能,对流靠流体整体移动传能;两者都需要物质。(M1)

真空中几乎没有粒子,故没有可碰撞的粒子链来跨越间隙传导能量。(A1)

间隙中没有流体,也无法形成受热流体上升、较冷流体下沉的对流循环。(A1)

(b) 镀银表面的作用 A1·A1

所涉机制是热辐射,它以电磁(红外)波形式穿越真空。(A1)

光亮的镀银表面发射率低,故是不良发射体、良好反射体:向外辐射很少能量,并把辐射反射回饮料一侧,从而减少辐射损失。(A1)

(c) 能穿越真空的机制 B1

辐射是唯一无需介质、因而能在真空中传能的机制。(B1)

要点。保温瓶是经典考题载体,因为每个设计特征恰好针对一种机制:真空间隙一举击败两种依赖物质的机制(传导与对流),而镀银则对付那唯一无需介质的机制(辐射)。描述特征前先点出机制名称,因为分数系于机制而非器物。
Q4HARDPaper 1Stefan-Boltzmann + Wien scaling斯特藩-玻尔兹曼与维恩缩放[6 marks]

Black body whose absolute temperature is doubled. (a) factor by which radiated power rises; (b) factor and direction of the peak-wavelength shift; (c) show a $300\ \mathrm{K}$ surface peaks in the infrared.黑体的绝对温度加倍。(a) 辐射功率增大的倍数;(b) 峰值波长变化的倍数与方向;(c) 证明 $300\ \mathrm{K}$ 表面在红外达峰。

Answers:答案:  (a) $\times 16$  ·  (b) $\times \tfrac{1}{2}$, peak moves to shorter wavelengths  ·  (c) $\lambda_{\max} \approx 9.7\ \mathrm{\mu m}$ (infrared)

(a) Power factor from $L = \sigma A T^{4}$ M1·A1

Power scales as the fourth power of absolute temperature, with $A$ fixed: $\dfrac{L_2}{L_1} = \left(\dfrac{2T}{T}\right)^{4}$. (M1)

$$ \frac{L_2}{L_1} = 2^{4} = 16. $$

The radiated power increases by a factor of $16$. (A1)

(b) Wien shift M1·A1

By $\lambda_{\max} T = $ constant, $\lambda_{\max} \propto 1/T$, so doubling $T$ multiplies $\lambda_{\max}$ by $\tfrac{1}{2}$. (M1)

The peak wavelength halves, so the peak moves to shorter wavelengths (toward the blue / ultraviolet end). (A1)

(c) Room-temperature peak M1·A1

Apply Wien's law at $T = 300\ \mathrm{K}$: (M1)

$$ \lambda_{\max} = \frac{2.9\times10^{-3}}{300} \approx 9.7\times10^{-6}\ \mathrm{m} = 9.7\ \mathrm{\mu m}. $$

This is far longer than the visible band ($400$ to $700\ \mathrm{nm}$), so the peak lies well into the infrared. (A1)

Insight. The two radiation laws scale in opposite directions: power climbs as $T^{4}$ while the peak wavelength falls as $1/T$. That single fact explains why a warming object both brightens dramatically and shifts colour from red toward blue. The room-temperature estimate ($\approx 10\ \mathrm{\mu m}$) is worth memorising: it is why everyday objects glow only in the infrared and why thermal cameras, not the eye, are needed to see body heat.

(a) 由 $L = \sigma A T^{4}$ 求功率倍数 M1·A1

$A$ 固定时功率按绝对温度的四次方变化:$\dfrac{L_2}{L_1} = \left(\dfrac{2T}{T}\right)^{4}$。(M1)

$$ \frac{L_2}{L_1} = 2^{4} = 16. $$

辐射功率增大为原来的 $16$ 倍。(A1)

(b) 维恩位移 M1·A1

由 $\lambda_{\max} T = $ 常数,$\lambda_{\max} \propto 1/T$,故 $T$ 加倍使 $\lambda_{\max}$ 乘以 $\tfrac{1}{2}$。(M1)

峰值波长减半,故峰值移向更短波长(朝蓝 / 紫外一端)。(A1)

(c) 室温峰值 M1·A1

在 $T = 300\ \mathrm{K}$ 应用维恩定律:(M1)

$$ \lambda_{\max} = \frac{2.9\times10^{-3}}{300} \approx 9.7\times10^{-6}\ \mathrm{m} = 9.7\ \mathrm{\mu m}. $$

这远长于可见光波段($400$ 至 $700\ \mathrm{nm}$),故峰值深入红外。(A1)

要点。两条辐射定律方向相反:功率随 $T^{4}$ 上升,而峰值波长随 $1/T$ 下降。这一事实解释了为何受热物体既急剧变亮、颜色又由红移向蓝。室温估值($\approx 10\ \mathrm{\mu m}$)值得记住:这正是日常物体只在红外发光、需要热像仪而非肉眼才能看到体热的原因。
PART II  ·  PAPER 1B / DATA ANALYSIS第二部分  ·  第一卷 B / 数据分析Graphs · data · uncertainties · 20 marks图像 · 数据 · 不确定度 · 20 分

Worked Solutions详细解析

Q5HARDPaper 1Bheating curve: plateau and slope加热曲线:平台与斜段[10 marks]

$0.10\ \mathrm{kg}$ solid heated at $40\ \mathrm{W}$; temperatures at $t = 0, 50, 100, 150, 200\ \mathrm{s}$ are $20, 60, 60, 60, 100\ ^{\circ}\mathrm{C}$. (a) melting interval, melting point, why $T$ is constant; (b) $c$ of the solid from the first slope; (c) latent heat of fusion from the plateau; (d) percentage uncertainty in power and its propagation.$0.10\ \mathrm{kg}$ 固体以 $40\ \mathrm{W}$ 加热;$t = 0, 50, 100, 150, 200\ \mathrm{s}$ 处温度为 $20, 60, 60, 60, 100\ ^{\circ}\mathrm{C}$。(a) 熔化区间、熔点、温度恒定的原因;(b) 由首段斜率求固体比热容;(c) 由平台求熔化潜热;(d) 功率的百分比不确定度及其传递。

Answers:答案:  (a) melts from $50\ \mathrm{s}$ to $150\ \mathrm{s}$; melting point $60\ ^{\circ}\mathrm{C}$  ·  (b) $c = 500\ \mathrm{J\,kg^{-1}\,K^{-1}}$  ·  (c) $L_{f} = 4.0\times10^{4}\ \mathrm{J\,kg^{-1}}$  ·  (d) $5\%$

(a) Melting interval and constant temperature A1·A1·R1

The temperature is flat at $60\ ^{\circ}\mathrm{C}$ from $t = 50\ \mathrm{s}$ to $t = 150\ \mathrm{s}$, so that plateau is the phase change: the substance melts over this interval. (A1)

The melting point is the plateau temperature, $60\ ^{\circ}\mathrm{C}$. (A1)

During melting the supplied energy goes entirely into breaking intermolecular bonds, raising the molecular potential energy, not the molecular kinetic energy. Since temperature tracks only the kinetic energy, it stays constant. (R1)

(b) Specific heat capacity of the solid M1·M1·A1

Over the first $50\ \mathrm{s}$ the energy supplied is $Q = Pt = (40)(50) = 2000\ \mathrm{J}$, and the temperature rises by $\Delta T = 60 - 20 = 40\ \mathrm{K}$. (M1)

Apply $Q = mc\Delta T$: (M1)

$$ c = \frac{Q}{m\,\Delta T} = \frac{2000}{(0.10)(40)} = 500\ \mathrm{J\,kg^{-1}\,K^{-1}}. $$

(A1)

(c) Latent heat of fusion M1·A1

The plateau lasts from $50\ \mathrm{s}$ to $150\ \mathrm{s}$, a duration of $100\ \mathrm{s}$, so $Q = Pt = (40)(100) = 4000\ \mathrm{J}$ all goes into melting. Apply $Q = mL_{f}$: (M1)

$$ L_{f} = \frac{Q}{m} = \frac{4000}{0.10} = 4.0\times10^{4}\ \mathrm{J\,kg^{-1}}. $$

(A1)

(d) Uncertainty in the power A1·R1

Percentage uncertainty in power: $\dfrac{2}{40}\times 100\% = 5\%$. (A1)

Since $L_{f} = Pt/m$ is directly proportional to $P$, the $5\%$ uncertainty in $P$ carries straight through, giving a $5\%$ uncertainty in $L_{f}$ (with $t$ and $m$ assumed precise). (R1)

Insight. A heating curve is read by phase: sloped sections obey $Q = mc\Delta T$ and flat plateaux obey $Q = mL$, with the constant power converting clock time into energy through $Q = Pt$. The plateau length is the whole story for latent heat. For uncertainty, a quantity built only by multiplication and division adds fractional uncertainties, so a lone $5\%$ input becomes a $5\%$ output unchanged.

(a) 熔化区间与温度恒定 A1·A1·R1

温度从 $t = 50\ \mathrm{s}$ 到 $t = 150\ \mathrm{s}$ 在 $60\ ^{\circ}\mathrm{C}$ 处保持水平,故该平台即相变:物质在此区间熔化。(A1)

熔点即平台温度 $60\ ^{\circ}\mathrm{C}$。(A1)

熔化期间供给的能量全部用于断裂分子间键、提升分子势能,而非分子动能。由于温度只反映动能,故保持不变。(R1)

(b) 固体的比热容 M1·M1·A1

前 $50\ \mathrm{s}$ 内供能 $Q = Pt = (40)(50) = 2000\ \mathrm{J}$,温升 $\Delta T = 60 - 20 = 40\ \mathrm{K}$。(M1)

用 $Q = mc\Delta T$:(M1)

$$ c = \frac{Q}{m\,\Delta T} = \frac{2000}{(0.10)(40)} = 500\ \mathrm{J\,kg^{-1}\,K^{-1}}. $$

(A1)

(c) 熔化潜热 M1·A1

平台从 $50\ \mathrm{s}$ 持续到 $150\ \mathrm{s}$,历时 $100\ \mathrm{s}$,故 $Q = Pt = (40)(100) = 4000\ \mathrm{J}$ 全部用于熔化。用 $Q = mL_{f}$:(M1)

$$ L_{f} = \frac{Q}{m} = \frac{4000}{0.10} = 4.0\times10^{4}\ \mathrm{J\,kg^{-1}}. $$

(A1)

(d) 功率的不确定度 A1·R1

功率的百分比不确定度:$\dfrac{2}{40}\times 100\% = 5\%$。(A1)

由于 $L_{f} = Pt/m$ 与 $P$ 成正比,$P$ 的 $5\%$ 不确定度直接传过去,使 $L_{f}$ 也有 $5\%$ 不确定度(设 $t$、$m$ 精确)。(R1)

要点。读加热曲线要按相态:斜段服从 $Q = mc\Delta T$,平台服从 $Q = mL$,恒定功率通过 $Q = Pt$ 把时间换成能量。平台长度就是潜热的全部依据。对不确定度,只由乘除构成的量相加分数不确定度,故单独的 $5\%$ 输入原样变成 $5\%$ 输出。
Q6HARDPaper 1Bgradient method + uncertainty斜率法与不确定度[10 marks]

$0.50\ \mathrm{kg}$ water, $90\ \mathrm{W}$ heater; temperature-time graph straight with gradient $0.040\ \mathrm{K\,s^{-1}}$. (a) show gradient $= P/(mc)$; (b) experimental $c$; (c) percentage and absolute uncertainty from gradient $\pm 0.002$; (d) why an imperfect beaker gives a value too high.$0.50\ \mathrm{kg}$ 水,$90\ \mathrm{W}$ 加热器;温度-时间图为直线,斜率 $0.040\ \mathrm{K\,s^{-1}}$。(a) 证明斜率 $= P/(mc)$;(b) 实测 $c$;(c) 由斜率 $\pm 0.002$ 求百分比与绝对不确定度;(d) 隔热不完美为何使值偏高。

Answers:答案:  (a) gradient $= \dfrac{P}{mc}$  ·  (b) $c = 4500\ \mathrm{J\,kg^{-1}\,K^{-1}}$  ·  (c) $5\%$, i.e. $\pm 200\ \mathrm{J\,kg^{-1}\,K^{-1}}$  ·  (d) heat lost is replaced more slowly, so $\Delta T$ per second is smaller

(a) Deriving the gradient relation M1·M1·A1

The heater delivers energy at a steady rate, so in time $t$ it supplies $Q = Pt$, and this energy heats the water: $Pt = mc\,\Delta T$. (M1)

Rearrange for the temperature change as a function of time: $\Delta T = \dfrac{P}{mc}\,t$. (M1)

This has the straight-line form $\Delta T = (\text{gradient})\times t$, so the gradient of the temperature-time graph is $\dfrac{P}{mc}$. (A1)

(b) Experimental specific heat capacity M1·A1

Rearrange gradient $= \dfrac{P}{mc}$ for $c$: (M1)

$$ c = \frac{P}{m\times\text{gradient}} = \frac{90}{(0.50)(0.040)} = 4500\ \mathrm{J\,kg^{-1}\,K^{-1}}. $$

(A1)

(c) Uncertainty in $c$ M1·A1·A1

With $P$ and $m$ precise, $c$ depends only on the gradient, and $c \propto 1/\text{gradient}$, so the fractional uncertainty in $c$ equals that in the gradient: (M1)

$$ \frac{\Delta c}{c} = \frac{0.002}{0.040} = 0.05 = 5\%. $$

(A1)

Absolute uncertainty: $\Delta c = 0.05\times 4500 = 200\ \mathrm{J\,kg^{-1}\,K^{-1}}$, so $c = (4500 \pm 200)\ \mathrm{J\,kg^{-1}\,K^{-1}}$. (A1)

(d) Why an imperfect beaker reads high B1·R1

If the beaker is not perfectly insulated, some energy leaks to the surroundings, so the water heats up more slowly and the measured gradient is smaller than the ideal $P/(mc)$. (B1)

Because $c \propto 1/\text{gradient}$, a smaller gradient gives a larger computed $c$, so the value comes out too high. (R1)

Insight. Putting the unknown into a gradient is the standard data-analysis move, because a best-fit line averages out random scatter far better than any single reading. The clean way to assign the uncertainty is to note which variable the result depends on: here only the gradient carries uncertainty, and an inverse relationship preserves the fractional figure ($5\%$ in, $5\%$ out). The systematic direction follows from the same inverse: losses lower the slope and so inflate $c$.

(a) 推导斜率关系 M1·M1·A1

加热器以恒定速率供能,故时间 $t$ 内供给 $Q = Pt$,此能量加热水:$Pt = mc\,\Delta T$。(M1)

解出温升随时间的关系:$\Delta T = \dfrac{P}{mc}\,t$。(M1)

此式形如 $\Delta T = (\text{斜率})\times t$,故温度-时间图的斜率为 $\dfrac{P}{mc}$。(A1)

(b) 实测比热容 M1·A1

由斜率 $= \dfrac{P}{mc}$ 解出 $c$:(M1)

$$ c = \frac{P}{m\times\text{斜率}} = \frac{90}{(0.50)(0.040)} = 4500\ \mathrm{J\,kg^{-1}\,K^{-1}}. $$

(A1)

(c) $c$ 的不确定度 M1·A1·A1

$P$、$m$ 精确时 $c$ 只依赖斜率,且 $c \propto 1/\text{斜率}$,故 $c$ 的分数不确定度等于斜率的:(M1)

$$ \frac{\Delta c}{c} = \frac{0.002}{0.040} = 0.05 = 5\%. $$

(A1)

绝对不确定度:$\Delta c = 0.05\times 4500 = 200\ \mathrm{J\,kg^{-1}\,K^{-1}}$,故 $c = (4500 \pm 200)\ \mathrm{J\,kg^{-1}\,K^{-1}}$。(A1)

(d) 隔热不完美为何偏高 B1·R1

若烧杯隔热不完美,部分能量泄漏到环境,故水升温更慢,测得斜率小于理想的 $P/(mc)$。(B1)

因 $c \propto 1/\text{斜率}$,斜率偏小使算得的 $c$ 偏大,故测值偏高。(R1)

要点。把未知量放进斜率是标准的数据分析手法,因为最佳拟合直线远比任何单点更能平均掉随机散布。指派不确定度的干净办法是看结果依赖哪个变量:这里只有斜率带不确定度,反比关系保持分数不变($5\%$ 进、$5\%$ 出)。系统方向也由同一反比给出:损失压低斜率从而抬高 $c$。
PART III  ·  PAPER 2 STYLE第三部分  ·  第二卷风格Extended structured · 39 marks长结构题 · 39 分

Worked Solutions详细解析

Q7HARDPaper 2method of mixtures混合法[10 marks]

$0.20\ \mathrm{kg}$ copper at $95\ ^{\circ}\mathrm{C}$ into $0.25\ \mathrm{kg}$ water at $18\ ^{\circ}\mathrm{C}$, insulated cup; $c_{\text{Cu}} = 385$, $c_{\text{water}} = 4180$. (a) state conservation of energy and the balance equation; (b) final temperature; (c) energy transferred; (d) why $T_f$ is near the water's temperature.$0.20\ \mathrm{kg}$、$95\ ^{\circ}\mathrm{C}$ 的铜投入 $0.25\ \mathrm{kg}$、$18\ ^{\circ}\mathrm{C}$ 的水,隔热杯;$c_{\text{Cu}} = 385$、$c_{\text{water}} = 4180$。(a) 陈述能量守恒与平衡方程;(b) 末温;(c) 传递的能量;(d) 为何末温接近水温。

Answers:答案:  (b) $T_{f} \approx 23.3\ ^{\circ}\mathrm{C}$  ·  (c) $Q \approx 5.5\times10^{3}\ \mathrm{J}$  ·  (d) water has both larger $m$ and larger $c$, so it dominates

(a) Conservation of energy R1·A1

In an insulated cup no energy leaves the system, so by conservation of energy the thermal energy lost by the cooling copper equals the thermal energy gained by the warming water. (R1)

Writing $T_{f}$ for the final temperature: $m_{\text{Cu}} c_{\text{Cu}} (95 - T_{f}) = m_{w} c_{w} (T_{f} - 18)$. (A1)

(b) Final equilibrium temperature M1·M1·M1·A1

Compute each heat-capacity product: $m_{\text{Cu}} c_{\text{Cu}} = (0.20)(385) = 77.0\ \mathrm{J\,K^{-1}}$ and $m_{w} c_{w} = (0.25)(4180) = 1045\ \mathrm{J\,K^{-1}}$. (M1)

Substitute: $77.0(95 - T_{f}) = 1045(T_{f} - 18)$. (M1)

$$ 7315 - 77.0\,T_{f} = 1045\,T_{f} - 18810. $$

Collect terms: $26125 = 1122\,T_{f}$. (M1)

$$ T_{f} = \frac{26125}{1122} \approx 23.3\ ^{\circ}\mathrm{C}. $$

(A1)

(c) Thermal energy transferred M1·A1

Use the copper's loss (equivalently the water's gain): $Q = m_{\text{Cu}} c_{\text{Cu}} (95 - T_{f}) = 77.0\,(95 - 23.3)$. (M1)

$$ Q = 77.0\times 71.7 \approx 5.5\times10^{3}\ \mathrm{J}. $$

(A1)

(d) Why $T_{f}$ sits near the water's value A1·R1

The final temperature lands at the heat-capacity-weighted average of the two starting temperatures, weighted by each body's $mc$. (R1)

The water's $mc = 1045\ \mathrm{J\,K^{-1}}$ is about $14$ times the copper's $77.0\ \mathrm{J\,K^{-1}}$, because the water has both more mass and a far larger specific heat capacity, so the mixture settles close to the water's $18\ ^{\circ}\mathrm{C}$. (A1)

Insight. The whole method is one line of energy conservation, $\text{loss} = \text{gain}$, with $Q = mc\Delta T$ on each side and each $\Delta T$ written as a positive drop or rise toward the common $T_{f}$. The single most common error is squaring the wrong sign by writing $(T_{f} - 95)$ for the hot body; keep both brackets positive by putting the larger temperature first for the cooler-down side. The result is always the $mc$-weighted mean, which is why the high-capacity body wins.

(a) 能量守恒 R1·A1

隔热杯中没有能量离开系统,故由能量守恒,降温的铜放出的热能等于升温的水吸收的热能。(R1)

设末温为 $T_{f}$:$m_{\text{Cu}} c_{\text{Cu}} (95 - T_{f}) = m_{w} c_{w} (T_{f} - 18)$。(A1)

(b) 最终平衡温度 M1·M1·M1·A1

先算各热容乘积:$m_{\text{Cu}} c_{\text{Cu}} = (0.20)(385) = 77.0\ \mathrm{J\,K^{-1}}$,$m_{w} c_{w} = (0.25)(4180) = 1045\ \mathrm{J\,K^{-1}}$。(M1)

代入:$77.0(95 - T_{f}) = 1045(T_{f} - 18)$。(M1)

$$ 7315 - 77.0\,T_{f} = 1045\,T_{f} - 18810. $$

合并同类项:$26125 = 1122\,T_{f}$。(M1)

$$ T_{f} = \frac{26125}{1122} \approx 23.3\ ^{\circ}\mathrm{C}. $$

(A1)

(c) 传递的热能 M1·A1

用铜的放热(等于水的吸热):$Q = m_{\text{Cu}} c_{\text{Cu}} (95 - T_{f}) = 77.0\,(95 - 23.3)$。(M1)

$$ Q = 77.0\times 71.7 \approx 5.5\times10^{3}\ \mathrm{J}. $$

(A1)

(d) 末温为何接近水温 A1·R1

末温落在两个初温按各自 $mc$ 加权的平均处。(R1)

水的 $mc = 1045\ \mathrm{J\,K^{-1}}$ 约为铜的 $77.0\ \mathrm{J\,K^{-1}}$ 的 $14$ 倍,因为水质量更大、比热容也大得多,故混合结果靠近水的 $18\ ^{\circ}\mathrm{C}$。(A1)

要点。整套方法就是一行能量守恒 $\text{放热} = \text{吸热}$,两侧各用 $Q = mc\Delta T$,每个 $\Delta T$ 写成朝共同 $T_{f}$ 的正降或正升。最常见错误是热体写成 $(T_{f} - 95)$ 而搞错符号;把较高温度放在降温侧的前面,保持两个括号都为正。结果总是 $mc$ 加权平均,故高热容物体取胜。
Q8HARDPaper 2mixed-phase calorimetry (ice + water)含相变量热(冰加水)[12 marks]

$0.030\ \mathrm{kg}$ ice at $0\ ^{\circ}\mathrm{C}$ added to $0.300\ \mathrm{kg}$ water at $25\ ^{\circ}\mathrm{C}$, well insulated; $L_{f} = 3.34\times10^{5}$, $c_{w} = 4180$. (a) energy to melt the ice; (b) max energy the water can release and show all ice melts; (c) final temperature; (d) effect of heat leaking in from a warm room.$0.030\ \mathrm{kg}$、$0\ ^{\circ}\mathrm{C}$ 的冰加入 $0.300\ \mathrm{kg}$、$25\ ^{\circ}\mathrm{C}$ 的水,隔热良好;$L_{f} = 3.34\times10^{5}$、$c_{w} = 4180$。(a) 熔冰所需能量;(b) 水可释放的最大能量并证明冰全熔;(c) 末温;(d) 温暖房间漏入热量的影响。

Answers:答案:  (a) $Q = 1.0\times10^{4}\ \mathrm{J}$  ·  (b) $Q_{\max} \approx 3.1\times10^{4}\ \mathrm{J} > $ melt energy, so all ice melts  ·  (c) $T_{f} \approx 15.5\ ^{\circ}\mathrm{C}$  ·  (d) $T_{f}$ would be higher

(a) Energy to melt the ice M1·A1

Melting at constant $0\ ^{\circ}\mathrm{C}$ uses $Q = m_{i} L_{f}$: (M1)

$$ Q = (0.030)(3.34\times10^{5}) = 1.0\times10^{4}\ \mathrm{J}. $$

(A1)

(b) Maximum energy from the water, and that all ice melts M1·A1·R1

The most the warm water can give up is by cooling all the way to $0\ ^{\circ}\mathrm{C}$: $Q_{\max} = m_{w} c_{w}\,\Delta T = (0.300)(4180)(25)$. (M1)

$$ Q_{\max} = 3.135\times10^{4}\ \mathrm{J} \approx 3.1\times10^{4}\ \mathrm{J}. $$

(A1)

Since $3.1\times10^{4}\ \mathrm{J}$ available exceeds the $1.0\times10^{4}\ \mathrm{J}$ needed to melt the ice, all the ice melts and energy is still left over, so the final temperature lies above $0\ ^{\circ}\mathrm{C}$. (R1)

(c) Final equilibrium temperature M1·M1·M1·A1·A1

Energy conservation: the warm water cools from $25\ ^{\circ}\mathrm{C}$ to $T_{f}$, supplying both the melting of the ice and the warming of the melt-water from $0\ ^{\circ}\mathrm{C}$ to $T_{f}$. (M1)

$$ m_{w} c_{w}(25 - T_{f}) = m_{i} L_{f} + m_{i} c_{w}(T_{f} - 0). $$

(M1 for the complete balance)

Substitute numbers: $1254(25 - T_{f}) = 1.002\times10^{4} + 125.4\,T_{f}$. (M1)

$$ 31350 - 1254\,T_{f} = 10020 + 125.4\,T_{f}. $$ $$ 21330 = 1379.4\,T_{f}. $$

(A1)

$$ T_{f} = \frac{21330}{1379.4} \approx 15.5\ ^{\circ}\mathrm{C}. $$

(A1)

(d) Effect of imperfect insulation A1·R1

If heat leaks in from a warmer room, the system gains extra energy beyond what the original water supplied. (R1)

That extra energy goes into the mixture after the ice has melted, raising the final equilibrium temperature above the ideal $15.5\ ^{\circ}\mathrm{C}$. (A1)

Insight. Mixed-phase calorimetry is decided first by a feasibility check: compare the energy needed to complete the phase change against the maximum the other body can supply. Only once you know the ice fully melts can you write a single linear balance for $T_{f}$; if the ice had been in excess, the answer would pin at $0\ ^{\circ}\mathrm{C}$ with ice left over. The trap is forgetting the second term $m_{i} c_{w}(T_{f} - 0)$: the melt-water must itself be warmed from $0\ ^{\circ}\mathrm{C}$ to the final temperature, using the specific heat of water.

(a) 熔冰所需能量 M1·A1

在恒定 $0\ ^{\circ}\mathrm{C}$ 熔化用 $Q = m_{i} L_{f}$:(M1)

$$ Q = (0.030)(3.34\times10^{5}) = 1.0\times10^{4}\ \mathrm{J}. $$

(A1)

(b) 水可释放的最大能量,及冰全熔 M1·A1·R1

温水最多能放出的能量是冷却到 $0\ ^{\circ}\mathrm{C}$:$Q_{\max} = m_{w} c_{w}\,\Delta T = (0.300)(4180)(25)$。(M1)

$$ Q_{\max} = 3.135\times10^{4}\ \mathrm{J} \approx 3.1\times10^{4}\ \mathrm{J}. $$

(A1)

由于可供的 $3.1\times10^{4}\ \mathrm{J}$ 超过熔冰所需的 $1.0\times10^{4}\ \mathrm{J}$,冰全部熔化且尚有能量剩余,故末温高于 $0\ ^{\circ}\mathrm{C}$。(R1)

(c) 最终平衡温度 M1·M1·M1·A1·A1

能量守恒:温水从 $25\ ^{\circ}\mathrm{C}$ 冷却到 $T_{f}$,既供熔冰又把化出的水从 $0\ ^{\circ}\mathrm{C}$ 升温到 $T_{f}$。(M1)

$$ m_{w} c_{w}(25 - T_{f}) = m_{i} L_{f} + m_{i} c_{w}(T_{f} - 0). $$

(完整平衡式得 M1)

代入数值:$1254(25 - T_{f}) = 1.002\times10^{4} + 125.4\,T_{f}$。(M1)

$$ 31350 - 1254\,T_{f} = 10020 + 125.4\,T_{f}. $$ $$ 21330 = 1379.4\,T_{f}. $$

(A1)

$$ T_{f} = \frac{21330}{1379.4} \approx 15.5\ ^{\circ}\mathrm{C}. $$

(A1)

(d) 隔热不完美的影响 A1·R1

若热量从较暖房间漏入,系统获得超出原有水所供的额外能量。(R1)

这部分额外能量在冰熔化后进入混合物,使末温高于理想的 $15.5\ ^{\circ}\mathrm{C}$。(A1)

要点。含相变量热先做可行性判断:把完成相变所需能量与另一物体可供的最大能量相比。只有确定冰全熔,才能写出关于 $T_{f}$ 的单一线性平衡式;若冰过量,答案会锁定在 $0\ ^{\circ}\mathrm{C}$ 并有冰剩余。陷阱是漏掉第二项 $m_{i} c_{w}(T_{f} - 0)$:化出的水自身还需用水的比热从 $0\ ^{\circ}\mathrm{C}$ 升到末温。
Q9HARDPaper 2star: Wien then Stefan-Boltzmann恒星:维恩接斯特藩-玻尔兹曼[11 marks]

Black-body star: spectral peak $420\ \mathrm{nm}$, radius $6.5\times10^{8}\ \mathrm{m}$. (a) surface temperature from Wien; (b) surface area; (c) luminosity from Stefan-Boltzmann; (d) apparent brightness at $d = 2.0\times10^{17}\ \mathrm{m}$ with the spreading assumption stated.黑体恒星:光谱峰值 $420\ \mathrm{nm}$,半径 $6.5\times10^{8}\ \mathrm{m}$。(a) 由维恩求表面温度;(b) 表面积;(c) 由斯特藩-玻尔兹曼求光度;(d) 距离 $d = 2.0\times10^{17}\ \mathrm{m}$ 处的视亮度并写出扩散假设。

Answers:答案:  (a) $T \approx 6900\ \mathrm{K}$  ·  (b) $A \approx 5.3\times10^{18}\ \mathrm{m^{2}}$  ·  (c) $L \approx 6.8\times10^{26}\ \mathrm{W}$  ·  (d) $b \approx 1.4\times10^{-9}\ \mathrm{W\,m^{-2}}$

(a) Surface temperature from Wien's law M1·A1

Convert the peak to metres, $\lambda_{\max} = 420\ \mathrm{nm} = 4.20\times10^{-7}\ \mathrm{m}$, then use $\lambda_{\max} T = 2.9\times10^{-3}\ \mathrm{m\,K}$: (M1)

$$ T = \frac{2.9\times10^{-3}}{4.20\times10^{-7}} \approx 6900\ \mathrm{K}. $$

(A1)

(b) Surface area of the star M1·A1

Treat the star as a sphere of radius $r = 6.5\times10^{8}\ \mathrm{m}$, $A = 4\pi r^{2}$: (M1)

$$ A = 4\pi (6.5\times10^{8})^{2} \approx 5.3\times10^{18}\ \mathrm{m^{2}}. $$

(A1)

(c) Luminosity from Stefan-Boltzmann M1·M1·A1

Use $L = \sigma A T^{4}$ with $T$ in kelvin: (M1)

$$ L = (5.67\times10^{-8})(5.3\times10^{18})(6900)^{4}. $$

(M1 for substitution; $(6900)^{4} \approx 2.27\times10^{15}$)

$$ L \approx 6.8\times10^{26}\ \mathrm{W}. $$

(A1)

(d) Apparent brightness at Earth M1·M1·A1·A1

Assume the radiation spreads uniformly over a sphere of radius $d$, so by the time it reaches Earth it is diluted over an area $4\pi d^{2}$. (M1)

Apparent brightness is power per unit area received: $b = \dfrac{L}{4\pi d^{2}}$. (M1)

$$ b = \frac{6.8\times10^{26}}{4\pi (2.0\times10^{17})^{2}} = \frac{6.8\times10^{26}}{5.03\times10^{35}}. $$

(A1)

$$ b \approx 1.4\times10^{-9}\ \mathrm{W\,m^{-2}}. $$

(A1)

Insight. This is the canonical two-law star chain: a measured spectral peak gives the temperature through Wien, and the temperature plus the size give the luminosity through Stefan-Boltzmann. The most-penalised slip is forgetting to convert the peak to metres or the temperature stays in non-kelvin, which then gets raised to the fourth power and wrecks the order of magnitude. Apparent brightness adds one more idea, the inverse-square dilution over $4\pi d^{2}$, the foundation of the stellar distance work later in Theme E.

(a) 由维恩定律求表面温度 M1·A1

把峰值换算成米,$\lambda_{\max} = 420\ \mathrm{nm} = 4.20\times10^{-7}\ \mathrm{m}$,再用 $\lambda_{\max} T = 2.9\times10^{-3}\ \mathrm{m\,K}$:(M1)

$$ T = \frac{2.9\times10^{-3}}{4.20\times10^{-7}} \approx 6900\ \mathrm{K}. $$

(A1)

(b) 恒星表面积 M1·A1

把恒星视为半径 $r = 6.5\times10^{8}\ \mathrm{m}$ 的球,$A = 4\pi r^{2}$:(M1)

$$ A = 4\pi (6.5\times10^{8})^{2} \approx 5.3\times10^{18}\ \mathrm{m^{2}}. $$

(A1)

(c) 由斯特藩-玻尔兹曼求光度 M1·M1·A1

用 $L = \sigma A T^{4}$,$T$ 取开尔文:(M1)

$$ L = (5.67\times10^{-8})(5.3\times10^{18})(6900)^{4}. $$

(代入得 M1;$(6900)^{4} \approx 2.27\times10^{15}$)

$$ L \approx 6.8\times10^{26}\ \mathrm{W}. $$

(A1)

(d) 地球处的视亮度 M1·M1·A1·A1

假设辐射均匀扩散到半径 $d$ 的球面上,故到达地球时已稀释到面积 $4\pi d^{2}$ 上。(M1)

视亮度即单位面积接收功率:$b = \dfrac{L}{4\pi d^{2}}$。(M1)

$$ b = \frac{6.8\times10^{26}}{4\pi (2.0\times10^{17})^{2}} = \frac{6.8\times10^{26}}{5.03\times10^{35}}. $$

(A1)

$$ b \approx 1.4\times10^{-9}\ \mathrm{W\,m^{-2}}. $$

(A1)

要点。这是经典的两定律恒星链:测得的光谱峰值经维恩给出温度,温度加尺寸经斯特藩-玻尔兹曼给出光度。最常被扣分的失误是忘把峰值换成米,或温度未用开尔文,再被四次方放大就毁掉数量级。视亮度再添一个观念,即在 $4\pi d^{2}$ 上的平方反比稀释,这是后续主题 E 中恒星距离工作的基础。
Q10HARDPaper 2internal energy + radiated power内能与辐射功率[6 marks]

Black-body filament, area $3.0\times10^{-5}\ \mathrm{m^{2}}$, steady $2500\ \mathrm{K}$. (a) power radiated; (b) why constant internal energy is consistent with energy flowing in and out; (c) factor by which an identical filament at $5000\ \mathrm{K}$ radiates more, justified.黑体灯丝,面积 $3.0\times10^{-5}\ \mathrm{m^{2}}$,稳定 $2500\ \mathrm{K}$。(a) 辐射功率;(b) 为何恒定内能与能量进出相容;(c) 同样灯丝在 $5000\ \mathrm{K}$ 辐射更多的倍数及理由。

Answers:答案:  (a) $P \approx 66\ \mathrm{W}$  ·  (b) input power $=$ radiated power, so $U$ is constant  ·  (c) $\times 16$

(a) Power radiated M1·A1

Use $L = \sigma A T^{4}$ with $T = 2500\ \mathrm{K}$: (M1)

$$ P = (5.67\times10^{-8})(3.0\times10^{-5})(2500)^{4} \approx 66\ \mathrm{W}. $$

(A1)

(b) Constant internal energy A1·R1

The internal energy of the filament depends on its temperature, which is steady, so $U$ does not change with time. (A1)

This is consistent with energy flowing through the filament because the electrical power delivered to it equals the power it radiates away: the inflow and outflow are balanced, so there is no net change in internal energy. (R1)

(c) Factor for the hotter filament M1·A1

The temperature ratio is $\dfrac{5000}{2500} = 2$, and power scales as $T^{4}$: (M1)

$$ \frac{P_2}{P_1} = 2^{4} = 16. $$

The hotter filament radiates $16$ times the power of the first. (A1)

Insight. A steady temperature is a statement about energy balance, not energy absence: a working filament is in a dynamic steady state where electrical input exactly matches radiative output, so internal energy is constant even though energy pours through continuously. The same $T^{4}$ scaling that drives the doubling factor of $16$ explains why a small rise in operating temperature dramatically increases a bulb's power draw and why incandescent lamps run so hot to emit visible light.

(a) 辐射功率 M1·A1

用 $L = \sigma A T^{4}$,$T = 2500\ \mathrm{K}$:(M1)

$$ P = (5.67\times10^{-8})(3.0\times10^{-5})(2500)^{4} \approx 66\ \mathrm{W}. $$

(A1)

(b) 内能恒定 A1·R1

灯丝的内能取决于其温度,而温度稳定,故 $U$ 不随时间变化。(A1)

这与能量流经灯丝相容,因为供给它的电功率等于它辐射出去的功率:进出平衡,故内能无净变化。(R1)

(c) 更热灯丝的倍数 M1·A1

温度比为 $\dfrac{5000}{2500} = 2$,功率按 $T^{4}$ 变化:(M1)

$$ \frac{P_2}{P_1} = 2^{4} = 16. $$

更热的灯丝辐射功率为第一根的 $16$ 倍。(A1)

要点。恒温说的是能量平衡,而非没有能量:工作中的灯丝处于动态稳态,电输入恰好等于辐射输出,故即便能量持续流过,内能仍恒定。驱动加倍因子 $16$ 的同一 $T^{4}$ 缩放,也解释了为何工作温度小升即大幅增加灯泡功耗,以及白炽灯为何须运行得如此之热才能发出可见光。